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This image shows the molecular structure of PCl 3 (left) and PCl 5 (right) in the gas phase. Like most other nonmetal halides, both phosphorus chlorides react with an excess of water and yield hydrogen chloride and an oxyacid: PCl 3 yields phosphorous acid H 3 PO 3 and PCl 5 yields phosphoric acid, H 3 PO 4 .

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Geometry of PCl 5 based on hybridization: The five sp 3 d hybrid orbitals orient themselves in a trigonal bipyramidal manner, which is the geometry of PCl 5. Notice that all the P−Cl bonds in the molecule are not equivalent. Three bonds that are present in one plane are called equatorial bonds and have an angle of 120° between them.

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Molecular geometry is the three-dimensional arrangement of the atoms that constitute a molecule.It includes the general shape of the molecule as well as bond lengths, bond angles, torsional angles and any other geometrical parameters that determine the position of each atom.. Molecular geometry influences several properties of a substance including its reactivity, polarity, phase of matter ...

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Jun 23, 2010 · Equilibrium molecular geometry of poly(ε-caprolactone) integrated spiropyran 5 in the spiro form. The effect of an applied stress was calculated by gradually increasing the distance between the methyl units (denoted by arrows) while optimizing...

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6. a) What is the molecular geometry of the species shown at left? b) Draw Lewis Dot Structures for each of the following species. (i) NO 3 – (ii) SeBr 3 – (iii) PCl 3: c) What is the VSEPR #, electron group arrangement, and molecular geometry for each of the above species?

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Other atoms that exhibit sp 3 d 2 hybridization include the phosphorus atom in PCl 6 −, the iodine atom in the interhalogens IF 6 +, IF 5, ICl 4 −, IF 4 −, and the xenon atom in XeF 4. This text has been adapted from Openstax, Chemistry 2e, Section 8.2: Hybrid Atomic Orbitals. 6. a) What is the molecular geometry of the species shown at left? b) Draw Lewis Dot Structures for each of the following species. (i) NO 3 – (ii) SeBr 3 – (iii) PCl 3: c) What is the VSEPR #, electron group arrangement, and molecular geometry for each of the above species?

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