Concerning Practice Problems. The practice problems provided as part of this text are chiefly interactive, and should provide a useful assessment of the reader's understanding at various stages in the development of the subject.
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Conference on Hyperconjugation. London, New York, Symposium Publications Division, Pergamon Press, 1959 (OCoLC)568662916 Online version: Conference on Hyperconjugation (1958 : Indiana University). Conference on Hyperconjugation. London, New York, Symposium Publications Division, Pergamon Press, 1959 (OCoLC)605557757: Material Type: Conference ...
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According to classical resonance theory, electron delocalization could occur only via parallel overlap of p orbitals. According to hyperconjugation, also known as no-bond resonance, and a variant of resonance theory, electron delocalization could also occur via parallel overlap of p orbitals with hybridized orbitals participating in sigma bonds.This mixing is dependent upon the nature of G and is most pronounced in the sulfonyl chlorides, where the energy of the SCl(sigma*) orbital is lowered by approximately 0.5 eV. The observed mixing is best described as excited-state hyperconjugation of the aryl pi system into the SCl(sigma*) orbital.